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Great Stuff Insulating Foam Sealant, Pond & Stone, Aerosol-01/04/2016
Products in this Consumer Product Information Database (CPID) are classified based on their composition:
Substances: single chemicals
Preparations: products which contain chemicals that can be easily separated during normal use
Articles: products or product assemblies that do not contain chemicals that can be separated out from the product or assembly under normal or advertised use.
Classification: Preparation
Indicates country where product is sold.
Market: US/CanadaGreat Stuff Insulating Foam Sealant, Pond & Stone bonds without mortar and helps direct water over, not under, rocks. Creates a water-shedding bond for stone, rock, masonry, concrete and other building materials. Safe for ornamental fish and plants.
Purpose of product.
Usage: Pond and waterway sealant.Structure such as solid, liquid, aerosol etc.
Form: aerosolDate when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
Date verified: February 15, 20242030 Willard H. Dow Center
Midland MI 48674
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Chemical Composition/Ingredients
The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
Advanced
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.-
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Percent of chemical in preparation.
% Conc.Chemical of Concern (CoC)
Chemical of Concern(CoC)Polymethylene polyphenyl isocyanate 009016-87-9 10.0-30.0 Yes 
CoC List
Methylene bisphenyl diisocyanate (MDI) 000101-68-8 10.0-30.0 Yes CoC List
Polymethylenepolyphenylisocyanate, propoxylated glycerin polymer 057029-46-6 10.0-30.0 No Isocyanic acid, polymethylenepolyphenylene ester, polymer with alpha-hydro-omega-hydroxypoly(oxy(methyl-1,2-ethanediyl)) 053862-89-8 10.0-30.0 No Tri-(2-chloroisopropyl)phosphate 013674-84-5 5.0-10.0 Yes CoC List
Chlorinated paraffin waxes 063449-39-8 5.0-10.0 Yes CoC List
Isobutane 000075-28-5 7.0-13.0 Yes CoC List
Dimethyl ether 000115-10-6 1.0-5.0 No Propane 000074-98-6 1.0-5.0 No -
Health Effects Information
Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Safety Data Sheet (SDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.
View Safety Data Sheet(SDS) Date that the Safety Data Sheet (SDS) was issued by manufacturer of a specific product.
SDS DATE :January 04, 2016 -
Warnings
Hazard Statements
Danger. Flammable aerosol. Contains gas under pressure; may explode if heated. Causes skin and eye irritation. May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. May cause harm to breast-fed children. May cause damage to organs (Respiratory Tract) through prolonged or repeated exposure if inhaled.
Precautionary Statements
Prevention
Obtain special instructions before use. Keep away from heat/sparks/open flames/hot surfaces. No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. Avoid contact during pregnancy/ while nursing. Wash skin thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves. In case of inadequate ventilation wear respiratory protection.
Response
IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/ attention. Take off contaminated clothing and wash before reuse.
IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unwell.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention.
IF exposed or concerned: Get medical advice/ attention.
Storage
Store in a well-ventilated place. Keep container tightly closed. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 deg C/ 122 deg F.
Disposal
Dispose of contents/ container to an approved waste disposal plant. -
Acute health effects
From SDS:
Hazards Identification
Emergency Overview
Flammable aerosol. Contains gas under pressure; may explode if heated. Causes skin and eye irritation. May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. May cause harm to breast-fed children. May cause damage to organs (Respiratory Tract) through prolonged or repeated exposure if inhaled
Potential Health Effects
Eye Contact: Serious eye damage/eye irritation. May cause eye irritation. May cause slight temporary corneal injury.
Skin Contact: Prolonged skin contact is unlikely to result in absorption of harmful amounts.
Inhalation: In confined or poorly ventilated areas, vapor can easily accumulate and can cause unconsciousness and death due to displacement of oxygen. Excessive exposure may cause irritation to upper respiratory tract (nose and throat) and lungs. May cause pulmonary edema (fluid in the lungs.) Effects may be delayed. May cause central nervous system depression. Symptoms of excessive exposure may be anesthetic or narcotic effects; dizziness and drowsiness may be observed. Excessive exposure may increase sensitivity to epinephrine and increase myocardial irritability (irregular heartbeats). Decreased lung function has been associated with overexposure to isocyanates.
Ingestion: Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal handling operations are not likely to cause injury; however, swallowing larger amounts may cause injury. -
Chronic health effects
From SDS:
Prolonged contact may cause moderate skin irritation with local redness. Material may stick to skin causing irritation upon removal. -
Carcinogenicity
Lung tumors have been observed in laboratory animals exposed to respirable aerosol droplets of MDI/Polymeric MDI (6 mg/m3) for their lifetime. Tumors occurred concurrently with respiratory irritation and lung injury. Current exposure guidelines are expected to protect against these effects reported for MDI.
Paraffin waxes and Hydrocarbon waxes, chlorinated: IARC Group 2B, Possibly carcinogenic to humans
Paraffin waxes and Hydrocarbon waxes, chlorinated: NTP, Reasonably anticipated to be a human carcinogen -
Handling information
Keep away from heat, sparks and flame. Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated contact with skin. Wash thoroughly after handling. Keep container closed. Use only with adequate ventilation. No smoking, open flames or sources of ignition in handling and storage area. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Contents under pressure. Do not puncture or incinerate container. Containers, even those that have been emptied, can contain vapors. Do not cut, drill, grind, weld, or perform similar operations on or near empty containers. Do not enter confined spaces unless adequately ventilated. Never use air pressure for transferring product. Use of non-sparking or explosion-proof equipment may be necessary, depending upon the type of operation. Minimize sources of ignition, such as static build-up, heat, spark or flame. Store in a dry place.
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Disposal information
DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local laws and regulations.
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California Prop. 65 Warning
This product contains no listed substances known to the State of California to cause cancer, birth defects or other reproductive harm, at levels which would require a warning under the statute.
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First Aid
Eye Contact: Immediately flush eyes with water; remove contact lenses, if present, after the first 5 minutes, then continue flushing eyes for at least 15 minutes. Obtain medical attention without delay, preferably from an ophthalmologist. Suitable emergency eye wash facility should be immediately available.
Skin contact: Remove material from skin immediately by washing with soap and plenty of water. Remove contaminated clothing and shoes while washing. Seek medical attention if irritation persists. Wash clothing before reuse. An MDI skin decontamination study demonstrated that cleaning very soon after exposure is important, and that a polyglycol-based skin cleanser or corn oil may be more effective than soap and water. Discard items which cannot be decontaminated, including leather articles such as shoes, belts and watchbands. Suitable emergency safety shower facility should be available in work area.
Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by qualified personnel. Call a physician or transport to a medical facility.
Ingestion: If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by medical personnel.
General Advice: First Aid responders should pay attention to self-protection and use the recommended protective clothing (chemical resistant gloves, splash protection).
Notes to Physician: Excessive exposure may aggravate preexisting asthma and other respiratory disorders (e.g. emphysema, bronchitis, reactive airways dysfunction syndrome). Repeated excessive exposure may aggravate preexisting lung disease. Maintain adequate ventilation and oxygenation of the patient. May cause respiratory sensitization or asthma-like symptoms. Bronchodilators, expectorants and antitussives may be of help. Treat bronchospasm with inhaled beta2 agonist and oral or parenteral corticosteroids. Respiratory symptoms, including pulmonary edema, may be delayed. Persons receiving significant exposure should be observed 24-48 hours for signs of respiratory distress. Exposure may increase "myocardial irritability". Do not administer sympathomimetic drugs such as epinephrine unless absolutely necessary. If you are sensitized to diisocyanates, consult your physician regarding working with other respiratory irritants or sensitizers. Although cholinesterase depression has been reported with this material, it is not of benefit in determining exposure and need not be considered in the treatment of persons exposed to the material. Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient.
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UN Global Harmonization Classification
